11–14 Aug 2025
Crowne Plaza Knoxville
US/Eastern timezone

Complexity in the medium-range order as a polyvalent liquid metal

Not scheduled
20m
Crowne Plaza Knoxville

Crowne Plaza Knoxville

401 W Summit Hill Dr SW, Knoxville, TN 37902
Contributed Talk

Speaker

Chengyun Hua (Oak Ridge National Laboratory)

Description

Gallium is a prototypical liquid metal and has gained resurgent attention due to its unique properties. Its atomic dynamics remain elusive despite a large number of studies, mainly due to the challenges of quantifying the atomic-scale dynamics of liquids. Recent developments in inelastic neutron scattering enable us to measure the Van Hove correlation function that describes the real-space motion of liquid atoms. In this work, we use this approach to reveal the dynamics in gallium liquids and find the co-existence of two medium-range orders (MROs), which have a distinct dynamical behavior from that of the short-range order (SRO). We propose that the two types of MRO are strongly overlapping in space and fluctuating in time and are the basis for anomalous behavior of liquid gallium. This view challenges the current view that liquid gallium consists of fluctuating metallic and insulating domains. These findings shed new light on the interpretation of similar microscopic anomalies observed in other semi-metallic liquids.

Topical Area Soft matter: polymers, and complex fluids

Author

Chengyun Hua (Oak Ridge National Laboratory)

Co-authors

Doug Abernathy (Oak Ridge National Laboratory) Eva Zarkadoula (Oak Ridge National Laboratory) Prof. Takeshi Egami (University of Tennessee at Knoxville) Dr Wojciech Dmowski (University of Tennessee at Knoxville) Yadu Krishnan Sarathchandran (University of Tennessee, Knoxville)

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